Product Name: Silicon Sulfide
Silicon Sulfide formular: SiS2
Silicon Sulfide molecular weight: 92.21
Silicon Sulfide density: 1.853 g/cm3
Silicon Sulfide melting point: 1090℃
Silicon Sulfide boiling point: 1130 ℃
Silicon Sulfide CAS NO. : 13759-10-9
Silicon Sulfide details:
Silicon sulfide, the molecular formula is SiS2. White fibrous orthorhombic or tetragonal crystals are stable at normal temperature and pressure and decomposed into SiO2 and H2S in the presence of moisture. It burns when heated in the air.
About Silicon Sulfide SiS2 Powder:
Silicon sulfide is an inorganic compound with the molecular formula Sis2.Sis2 = 92.21, colorless acicular crystal.The relative density is 2.02, the melting point is 1090℃, and it sublimates in nitrogen at 1250℃. Insoluble in benzene; Soluble in dilute base. Hydrolysis and ammonolysis occurred with water, ethanol and liquid ammonia, respectively. Reaction with alkali metal sulfides to form thiosilicates.Like silicon dioxide, the material is polymerized, but it uses a one-dimensional structure that is distinct from the usual silicon dioxide form.
Like other silicosulfide compounds, such as bis (trimethylsilyl) sulfides, SiS2 is easy to decompose to release hydrogen sulfide. In liquid ammonia, it has been reported to form imide Si(NH)2 and NH4SH, but recent reports have identified the crystallization (NH4)2[SIS3 (NH3)]·2NH3 as a product containing the tetrahedral orthosilicate anion, SIS3 (NH3).
Tetraethyl orthosilicate and H2S were synthesized by reaction with ethanol. With a large volume of tert-butyl alcohol, alcoholysis to obtain tri (tert-butyl) silicon mercaptan:
3 (CH3)3COH + Sis2 →[(CH3)3CO] 3Sish + H2S
Reaction with sodium sulfide, magnesium sulfide and aluminum sulfide to give sulphosilicate. Feel free to send an inquiry to get the latest price if you would like to buy Silicon Sulfide SiS2 Powder in bulk.
How is Silicon Sulfide SiS2 Powder produced?
1. Put aluminum powder and excess sulfur into the crucible and burn it to get aluminum sulfide. The aluminum sulfide is crushed and mixed with slightly excessive silica sand. Place the mixture in a shingle, then place the shingle in a quartz tube, and heat the quartz tube while injecting a small amount of dry nitrogen. The reaction starts at 1100℃, and the sublimated Sis2 adheres to the low-temperature region of the tube at 1200 ~ 1300℃. When purified, it is sublimated again in nitrogen or vacuum. Tetragonal Sis2 can be prepared by heating the mixture of silicon and sulfur at 5×103MPa and 700℃.
2. Decompose hydrocarbon self-based silicon by heating to generate silicon disulfide and sulfide at 250 ~ 300℃.If sulfur is added, it decomposes at a lower temperature. Si-disulfide and ethylthioane (C2H5-S2-C2H5, C2H5-S3-C2H5) are produced by mixing 96g sulfur with 39g Si(SC2H5)4 and heating it at 200℃ for 10min. The latter is dissolved in benzene and filtered to prevent it from mixing with moisture.
Applications of Silicon Sulfide SiS2 Powder:
Silicon sulfide is a medium water and acid soluble source of silicon used for compatibility with sulfates. Sulfate is a sulfate or ester formed by replacing one or two hydrogens with a metal.
Storage Condition of Silicon Sulfide SiS2 Powder:
The damp reunion will affect SiS2 powder dispersion performance and using effects, therefore, Silicon Sulfide SiS2 Powder should be sealed in vacuum packing and stored in a cool and dry room, the Silicon Sulfide SiS2 Powder can not be exposure to air. In addition, the Silicon Sulfide SiS2 Powdershould be avoided under stress.
Packing & Shipping of Silicon Sulfide SiS2 Powder:
We have many different kinds of packing which depend on the Silicon Sulfide SiS2 Powder quantity.
Silicon Sulfide SiS2 Powder packing:vacuum packing, 100g, 500g or 1kg/bag, 25kg/barrel, or as your request.
Silicon Sulfide SiS2 Powder shipping: could be shipped out by sea, by air, by express, as soon as possible once payment receipt.
Silicon Sulfide Properties
|Other Names||silicon(IV) sulfide, silicon disulfide, silicon(IV) sulphide, SiS2 powder|
|Solubility in H2O||Decomposes|
Silicon Sulfide Health & Safety Information
|Hazard Codes||F, T|
|Transport Information||UN3134 4.3+6.1/PG II|